In this section
Some of the covers featuring our work are shown below:
Wilton-Ely J, 2006, Dinuclear ruthenium and osmium compounds with metal-metal bonds, Comprehensive Organometallic Chemistry III, Editor(s): Crabtree, Mingos, Elsevier, Pages:647-716, ISBN:978-0080445908
@article{Mognon:2019:10.1016/j.jorganchem.2019.02.003,
author = {Mognon, L and Richardson, S and Agonigi, G and Bond, T and Marchetti, F and Wilton-Ely, J},
doi = {10.1016/j.jorganchem.2019.02.003},
journal = {Journal of Organometallic Chemistry},
pages = {9--12},
title = {Heterotrimetallic complexes of iron and ruthenium based on vinyliminium dithiocarboxylate ligands},
url = {http://dx.doi.org/10.1016/j.jorganchem.2019.02.003},
volume = {886},
year = {2019}
}
TY - JOUR
AB - The diiron vinyliminium compounds [Fe2{μ-η1:η3-C(R2)=C(H)C=N(Me)R1}(μ-CO)(CO)(Cp)2]OSO2CF3 (R1=Xyl=2,6-C6H3Me2, R2=Me; R1=Me, R2=CO2Me) provide a versatile entry point for many subsequent transformations, such as their reaction with carbon disulfide to provide zwitterionic dithiocarboxylate products. These compounds react with the coordinatively-unsaturated ruthenium vinyl precursors [Ru(CH=CHR3)Cl(CO)(PPh3)2] (R3=C6H4Me-4, 1-Pyrenyl) to yield heterotrimetallic Fe2Ru compounds, exhibiting vinyl moieties at both iron and ruthenium centres. The emission associated with the pyrenyl unit is enhanced in the diiron vinyliminium ruthenium pyrenyl complex compared to the diethyldithiocarbamate analogue.
AU - Mognon,L
AU - Richardson,S
AU - Agonigi,G
AU - Bond,T
AU - Marchetti,F
AU - Wilton-Ely,J
DO - 10.1016/j.jorganchem.2019.02.003
EP - 12
PY - 2019///
SN - 0022-328X
SP - 9
TI - Heterotrimetallic complexes of iron and ruthenium based on vinyliminium dithiocarboxylate ligands
T2 - Journal of Organometallic Chemistry
UR - http://dx.doi.org/10.1016/j.jorganchem.2019.02.003
UR - http://hdl.handle.net/10044/1/67396
VL - 886
ER -