In this section
@article{Fandiño:2015:10.1016/j.ijggc.2015.02.018,
author = {Fandiño, O and Trusler, JPM and Vega-Maza, D},
doi = {10.1016/j.ijggc.2015.02.018},
journal = {International Journal of Greenhouse Gas Control},
pages = {78--92},
title = {Phase behavior of (CO2 + H-2) and (CO2+ N-2) at temperatures between (218.15 and 303.15)K at pressures up to 15 MPa},
url = {http://dx.doi.org/10.1016/j.ijggc.2015.02.018},
volume = {36},
year = {2015}
}
TY - JOUR
AB - Vapor–liquid equilibrium data are reported for the binary systems (CO2 + H2) and (CO2 + N2) at temperatures between (218.15 and 303.15) K at pressures ranging from the vapor pressure of CO2 to approximately 15 MPa. These data were measured in a new analytical apparatus which is described in detail. The results are supported by a rigorous assessment of uncertainties and careful validation measurements. The new data help to resolve discrepancies between previous studies, especially for the (CO2 + H2) system. Experimental measurements of the three-phase solid–liquid–vapor locus are also reported for both binary systems.The vapor–liquid equilibrium data are modeled with the Peng–Robinson (PR) equation of state with two binary interaction parameters: one, a linear function of inverse temperature, applied to the unlike term in the PR attractive-energy parameter; and the other, taken to be constant, applied to the unlike term in the PR co-volume parameter. This model is able to fit the experimental data in a satisfactory way except in the critical region. We also report alternative binary parameter sets optimized for improved performance at either temperatures below 243 K or temperatures above 273 K. A simple predictive model for the three-phase locus is also presented and compared with the experimental data.
AU - Fandiño,O
AU - Trusler,JPM
AU - Vega-Maza,D
DO - 10.1016/j.ijggc.2015.02.018
EP - 92
PY - 2015///
SN - 1750-5836
SP - 78
TI - Phase behavior of (CO2 + H-2) and (CO2+ N-2) at temperatures between (218.15 and 303.15)K at pressures up to 15 MPa
T2 - International Journal of Greenhouse Gas Control
UR - http://dx.doi.org/10.1016/j.ijggc.2015.02.018
UR - http://hdl.handle.net/10044/1/23572
VL - 36
ER -