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Conference paperEstela-Uribe JF, Trusler JPM, 2001,
Extended corresponding states equation of state for natural gas systems
, 14th Symposium on Thermophysical Properties, Publisher: ELSEVIER SCIENCE BV, Pages: 21-29, ISSN: 0378-3812- Author Web Link
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- Citations: 16
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Conference paperFenghour A, Trusler JPM, Wakeham WA, 2001,
Densities and bubble points of ternary mixtures of methane, <i>n</i>-butane and <i>n</i>-hexadecane and quaternary mixtures of methane, <i>n</i>-butane, <i>n</i>-heptane and <i>n</i>-hexadecane
, 16th IUPAC Conference on Chemical Thermodynamics (ICCT-2000), Publisher: ELSEVIER SCIENCE BV, Pages: 111-119, ISSN: 0378-3812- Author Web Link
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- Citations: 10
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Conference paperBall SJ, Trusler JPM, 2001,
Speed of sound of <i>n</i>-hexane and <i>n</i>-hexadecane at temperatures between 298 and 373 K and pressures up to 100 MPa
, 14th Symposium on Thermophysical Properties, Publisher: KLUWER ACADEMIC/PLENUM PUBL, Pages: 427-443, ISSN: 0195-928X- Author Web Link
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- Citations: 78
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Journal articleTrusler JPM, 2000,
3 The virial equation of state
, Experimental Thermodynamics, Vol: 5, Pages: 35-74, ISSN: 1874-5644In one sense, being restricted to gases at low and moderate densities, the virial equation of state is of rather limited application. Nevertheless, it has the merits of a sound theoretical basis, a large database of experimentally-determined virial coefficients, and the ability to describe mixtures exactly. The relations set out in Table 3.2 may be used to express a wide range of thermodynamic properties of pure gases and mixtures in terms of the virial coefficients, their temperature derivatives and the heat capacity of the ideal gas. The virial coefficients may be obtained from experiment, from knowledge of the intermolecular potential-energy functions or from the principle of corresponding states. The relations between the virial coefficients and intermolecular forces is of real importance and has therefore been explored in detail. Equations (3.52), (3.54), and (3.55) may be used to determine B and C from u12 and Δu3 at temperatures where quantum corrections are unimportant. Quantum effects have also been considered above in sufficient detail to permit their calculation for the atomic and molecular systems of interest. Because such calculations can now be performed routinely, even for non-spherical molecules, it is perfectly feasible to represent the equation of state correct at least to the third virial coefficient by means of prescribed pair and triplet potentials. © 2000 Elsevier B.V. All rights reserved.
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Journal articleEwing MB, Trusler JPM, 2000,
Primary acoustic thermometry between <i>T</i>=90 K and <i>T</i>=300 K
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 32, Pages: 1229-1255, ISSN: 0021-9614- Author Web Link
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- Citations: 39
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Journal articleEstela-Uribe JF, Trusler JPM, 2000,
Acoustic and volumetric virial coefficients of nitrogen
, INTERNATIONAL JOURNAL OF THERMOPHYSICS, Vol: 21, Pages: 1033-1044, ISSN: 0195-928X- Author Web Link
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- Citations: 20
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Journal articlePádua AAH, Trusler JPM, 2000,
Nonadditive intermolecular potential and thermodynamic properties of ethane
, JOURNAL OF CHEMICAL PHYSICS, Vol: 113, Pages: 312-319, ISSN: 0021-9606- Author Web Link
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- Citations: 4
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Book chapterTrusler JPM, 2000,
The virial equation of state
, Experimental Thermodynamics, Vol. 5: Equations of state for fluids and fluid mixtures. Part I, Editors: Sengers, Kayser, Peters, White Jr, Amsterdam, Publisher: Elsevier, Pages: 35-74, ISBN: 9780444503848 -
Journal articleFenghour A, Trusler JPM, Wakeham WA, 1999,
Phase behaviour and density of (methane plus <i>n</i>-butane)
, FLUID PHASE EQUILIBRIA, Vol: 163, Pages: 139-156, ISSN: 0378-3812- Author Web Link
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- Citations: 17
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Conference paperFenghour A, Trusler JPM, Wakeham WA, 1999,
Phase behaviour and density of model reservoir fluids at high temperature and pressure
, 8th International Conference on Properties and Phase Equilibria for Product and Process Design, Publisher: ELSEVIER SCIENCE BV, Pages: 783-794, ISSN: 0378-3812- Author Web Link
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- Citations: 3
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Journal articleEstrada-Alexanders AF, Trusler JPM, 1999,
Speed of sound in (0.4C<sub>2</sub>H<sub>6</sub>+0.6CO<sub>2</sub>) at temperatures between <i>T</i>=220 K and <i>T</i>=450 K and pressures up to <i>p</i>=1.2 MPa
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 31, Pages: 685-695, ISSN: 0021-9614- Author Web Link
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- Citations: 6
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Book chapterTrusler JPM, 1999,
Solutions and blends of polymers
, Chemical Thermodynamics, Editors: Letcher, Oxford, Publisher: Blackwell Science, Pages: 197-208, ISBN: 9780632051274 -
Journal articleEstrada-Alexanders AF, Trusler JPM, 1998,
Speed of sound in carbon dioxide at temperatures between (220 and 450) K and pressures up to 14 MPa
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 30, Pages: 1589-1601, ISSN: 0021-9614- Author Web Link
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- Citations: 42
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Conference paperEstela-Uribe JF, Trusler JPM, 1998,
Shape factors for the light hydrocarbons
, 13th Symposium on Thermophysical Properties, Publisher: ELSEVIER SCIENCE BV, Pages: 225-234, ISSN: 0378-3812- Author Web Link
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- Citations: 9
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Journal articleGomes MFC, Trusler JPM, 1998,
The speed of sound in two methane-rich gas mixtures at temperatures between 250 K and 350 K and at pressures up to 20 MPa
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 30, Pages: 1121-1129, ISSN: 0021-9614- Author Web Link
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- Citations: 13
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Journal articleGomes MFC, Trusler JPM, 1998,
The speed of sound in nitrogen at temperatures between T = 250 K and T = 350 K and at pressures up to 30 MPa
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 30, Pages: 527-534, ISSN: 0021-9614- Author Web Link
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- Citations: 19
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Journal articleEstradaAlexanders AF, Trusler JPM, 1997,
The speed of sound and derived thermodynamic properties of ethane at temperatures between 220 K and 450 K and pressures up to 10.5 MPa
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 29, Pages: 991-1015, ISSN: 0021-9614- Author Web Link
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- Citations: 52
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Journal articledeBruijn R, vanDiest RJJ, Karapantsios TD, et al., 1997,
Heat transfer in pure critical fluids surrounded by finitely conducting boundaries in microgravity
, PHYSICA A, Vol: 242, Pages: 119-140, ISSN: 0378-4371- Author Web Link
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- Citations: 13
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Journal articleTrusler JPM, 1997,
Equation of state for gaseous propane determined from the speed of sound
, INTERNATIONAL JOURNAL OF THERMOPHYSICS, Vol: 18, Pages: 635-654, ISSN: 0195-928X- Author Web Link
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- Citations: 27
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Journal articleTrusler JPM, Wakeham WA, Zarari MP, 1997,
Model intermolecular potentials and virial coefficients determined from the speed of sound
, MOLECULAR PHYSICS, Vol: 90, Pages: 695-703, ISSN: 0026-8976- Author Web Link
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- Citations: 25
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Conference paperMichels AC, de Bruijn R, Karapantsios TD, et al., 1997,
Adiabatic compressive heating of critical fluids under microgravity conditions
, Pages: 137-145, ISSN: 0272-5673In this paper we report initial results from space experiments in which heat transport in near-critical SF6 was studied. The experiment utilized the Critical Point Facility (CPF) which was flown aboard ESA's Spacelab in the cargo bay of the Space Shuttle Columbia during the 1994 IML-2 mission. We report temperature and density measurements made during a number of transient heating runs in which energy was supplied by a plane heater immersed in the sample. Temperature measurements were made with a resolution of 10 μK by means of a set of five thermistors while density changes in the sample were monitored interferometrically. The results of these measurements show clearly that diffusive heat transfer slows dramatically as one approaches the critical point and that only a thin boundary layer adjacent to the heater is influenced directly by thermal conduction. We also observe clear evidence of the so-called adiabatic or piston-effect which results in a spatially-uniform temperature and density rise in the bulk of the fluid. The adiabatic temperature rise is shown to be essentially linear in time, synchronous with the heating and proportional to the heater power. The magnitude of the temperature rise is found to be consistent with theory, only when heat losses are taken into account.
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Journal articleEstradaAlexanders AF, Trusler JPM, 1996,
Thermodynamic properties of gaseous argon at temperatures between 110 and 450 K and densities up to 6.8 mold center dot dm(-3) determined from the speed of sound
, INTERNATIONAL JOURNAL OF THERMOPHYSICS, Vol: 17, Pages: 1325-1347, ISSN: 0195-928X- Author Web Link
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- Citations: 39
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Journal articlePadua AAH, Trusler JPM, 1996,
Application of integral equation theories to the nitrogen molecule
, JOURNAL OF CHEMICAL PHYSICS, Vol: 105, Pages: 5956-5967, ISSN: 0021-9606- Author Web Link
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- Citations: 3
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Journal articleTrusler JPM, Zarari MP, 1996,
The speed of sound in gaseous propane at temperatures between 225 K and 375 K and at pressures up to 0.8 MPa
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 28, Pages: 329-335, ISSN: 0021-9614- Author Web Link
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- Citations: 33
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Conference paperTrusler JPM, Wakeham WA, Zarari MP, 1996,
Second and third interaction virial coefficients of the (methane plus propane) system determined from the speed of sound
, 12th Symposium on Thermophysical Properties, Publisher: PLENUM PUBL CORP, Pages: 35-42, ISSN: 0195-928X- Author Web Link
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- Citations: 23
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BookAssael MJ, Trusler JPM, Tsolakis TF, 1996,
Thermophysical properties of fluids: an introduction to their prediction
, London, Publisher: Imperial College Press, ISBN: 9781860940095 -
Journal articleESTRADAALEXANDERS AF, TRUSLER JPM, 1995,
THE SPEED OF SOUND IN GASEOUS ARGON AT TEMPERATURES BETWEEN 110 K AND 450 K AND AT PRESSURES UP TO 19 MPA
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 27, Pages: 1075-1089, ISSN: 0021-9614- Author Web Link
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- Citations: 62
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Journal articleTRUSLER JPM, ZARARI MP, 1995,
2ND AND 3RD ACOUSTIC VIRIAL-COEFFICIENTS OF METHANE AT TEMPERATURES BETWEEN 125 K AND 375 K
, JOURNAL OF CHEMICAL THERMODYNAMICS, Vol: 27, Pages: 771-778, ISSN: 0021-9614- Author Web Link
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- Citations: 21
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Conference paperESTRADAALEXANDERS AF, TRUSLER JPM, ZARARI MP, 1995,
DETERMINATION OF THERMODYNAMIC PROPERTIES FROM THE SPEED OF SOUND
, 12th Symposium on Thermophysical Properties, Publisher: PLENUM PUBL CORP, Pages: 663-673, ISSN: 0195-928X- Author Web Link
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- Citations: 27
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Conference paperCUSCO L, TRUSLER JPM, 1995,
IDENTIFICATION OF ENVIRONMENTALLY ACCEPTABLE LOW-SOUND SPEED LIQUIDS
, 12th Symposium on Thermophysical Properties, Publisher: PLENUM PUBL CORP, Pages: 675-685, ISSN: 0195-928X- Author Web Link
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- Citations: 7
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