In this section
@article{Zhou:2020:10.1038/s41467-020-15991-6,
author = {Zhou, T and Wu, C and Wang, Y and Tomsia, AP and Li, M and Saiz, E and Fang, S and Baughman, RH and Jiang, L and Cheng, Q},
doi = {10.1038/s41467-020-15991-6},
journal = {Nature Communications},
title = {Super-tough MXene-functionalized graphene sheets},
url = {http://dx.doi.org/10.1038/s41467-020-15991-6},
volume = {11},
year = {2020}
}
TY - JOUR
AB - Flexible reduced graphene oxide (rGO) sheets are being considered for applications in portable electrical devices and flexible energy storage systems. However, the poor mechanical properties and electrical conductivities of rGO sheets are limiting factors for the development of such devices. Here we use MXene (M) nanosheets to functionalize graphene oxide platelets through Ti-O-C covalent bonding to obtain MrGO sheets. A MrGO sheet was crosslinked by a conjugated molecule (1-aminopyrene-disuccinimidyl suberate, AD). The incorporation of MXene nanosheets and AD molecules reduces the voids within the graphene sheet and improves the alignment of graphene platelets, resulting in much higher compactness and high toughness. In situ Raman spectroscopy and molecular dynamics simulations reveal the synergistic interfacial interaction mechanisms of Ti-O-C covalent bonding, sliding of MXene nanosheets, and π-π bridging. Furthermore, a supercapacitor based on our super-tough MXene-functionalized graphene sheets provides a combination of energy and power densities that are high for flexible supercapacitors.
AU - Zhou,T
AU - Wu,C
AU - Wang,Y
AU - Tomsia,AP
AU - Li,M
AU - Saiz,E
AU - Fang,S
AU - Baughman,RH
AU - Jiang,L
AU - Cheng,Q
DO - 10.1038/s41467-020-15991-6
PY - 2020///
SN - 2041-1723
TI - Super-tough MXene-functionalized graphene sheets
T2 - Nature Communications
UR - http://dx.doi.org/10.1038/s41467-020-15991-6
UR - https://www.ncbi.nlm.nih.gov/pubmed/32350273
UR - http://hdl.handle.net/10044/1/79206
VL - 11
ER -