Citation

BibTex format

@article{Stojanović:2024:10.1103/PhysRevX.14.021021,
author = {Stojanovi, L and Coker, J and Giannini, S and Londi, G and Gertsen, AS and Wenzel, Andreasen J and Yan, J and D'Avino, G and Beljonne, D and Nelson, J and Blumberger, J},
doi = {10.1103/PhysRevX.14.021021},
journal = {Physical Review X},
title = {Disorder-Induced Transition from Transient Quantum Delocalization to Charge Carrier Hopping Conduction in a Nonfullerene Acceptor Material},
url = {http://dx.doi.org/10.1103/PhysRevX.14.021021},
volume = {14},
year = {2024}
}

RIS format (EndNote, RefMan)

TY  - JOUR
AB - Nonfullerene acceptors have caused a step change in organic optoelectronics research but little is known about the mechanism and factors limiting charge transport in these molecular materials. Here a joint computational-experimental investigation is presented to understand the impact of various sources of disorder on the electron transport in the nonfullerene acceptor O-IDTBR. We find that in single crystals of this material, electron transport occurs in the transient quantum delocalization regime with the excess charge delocalized over about three molecules on average, according to quantum-classical nonadiabatic molecular-dynamics simulations. In this regime, carrier delocalization and charge mobility (μa=7 cm2 V-1 s-1) are limited by dynamical disorder of off-diagonal and diagonal electron-phonon coupling. In molecular assemblies representing disordered thin films, the additional static disorder of off-diagonal electron-phonon coupling is sufficient to fully localize the excess electron on single molecules, concomitant with a transition of transport mechanism from transient quantum delocalization to small polaron hopping and a drop in electron mobility by about 1 order of magnitude. Yet, inclusion of static diagonal disorder resulting from electrostatic interactions arising from the acceptor-donor-acceptor (A-D-A) structure of O-IDTBR, are found to have the most dramatic impact on carrier mobility, resulting in a further drop of electron mobility by about 4-5 orders of magnitude to 10-5 cm2 V-1 s-1, in good agreement with thin-film electron mobility estimated from space-charge-limited-current measurements. Limitations due to diagonal disorder caused by electrostatic interactions are likely to apply to most nonfullerene acceptors. They imply that while A-D-A or A-DAD-A motifs are beneficial for photoabsorption and exciton transport, the electrostatic disorder they create can limit carrier transport in thin-film optoelectronic applications. This work shows the va
AU - Stojanovi,L
AU - Coker,J
AU - Giannini,S
AU - Londi,G
AU - Gertsen,AS
AU - Wenzel,Andreasen J
AU - Yan,J
AU - D'Avino,G
AU - Beljonne,D
AU - Nelson,J
AU - Blumberger,J
DO - 10.1103/PhysRevX.14.021021
PY - 2024///
TI - Disorder-Induced Transition from Transient Quantum Delocalization to Charge Carrier Hopping Conduction in a Nonfullerene Acceptor Material
T2 - Physical Review X
UR - http://dx.doi.org/10.1103/PhysRevX.14.021021
VL - 14
ER -

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