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• Journal article
  Zhao N, Noh Y-Y, Chang J-F, Heeney M, McCulloch I, Sirringhaus Het al., 2009,

  Polaron Localization at Interfaces in High-Mobility Microcrystalline Conjugated Polymers

  , ADVANCED MATERIALS, Vol: 21, Pages: 3759-3763, ISSN: 0935-9648
  • Author Web Link
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  • Citations: 94
• Journal article
  Ball JM, Woebkenberg PH, Colleaux F, Heeney M, Anthony JE, McCulloch I, Bradley DDC, Anthopoulos TDet al., 2009,

  Solution processed low-voltage organic transistors and complementary inverters

  , APPLIED PHYSICS LETTERS, Vol: 95, ISSN: 0003-6951
  • Author Web Link
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  • Citations: 25
• Journal article
  Kim Y, Nelson J, Zhang T, Cook S, Durrant JR, Kim H, Park J, Shin M, Nam S, Heeney M, McCulloch I, Ha C-S, Bradley DDCet al., 2009,

  Distorted Asymmetric Cubic Nanostructure of Soluble Fullerene Crystals in Efficient Polymer:Fullerene Solar Cells

  , ACS NANO, Vol: 3, Pages: 2557-2562, ISSN: 1936-0851
  • Author Web Link
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  • Citations: 64
• Journal article
  Heeney M, Al-Hashimi M, McCulloch I, Zhang W, Hamilton Ret al., 2009,

  Structural and optoelectronic effects of chalcogen atom manipulation on low bandgap polymers

  , ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Vol: 238, ISSN: 0065-7727
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• Journal article
  Cates NC, Gysel R, Beiley Z, Miller CE, Toney MF, Heeney M, McCulloch I, McGehee MDet al., 2009,

  Intercalation in polymer-molecule blends

  , ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Vol: 238, ISSN: 0065-7727
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• Journal article
  Zhang W, Smith J, Hamilton R, Heeney M, Kirkpatrick J, Song K, Watkins SE, Anthopoulos T, McCulloch Iet al., 2009,

  Systematic Improvement in Charge Carrier Mobility of Air Stable Triarylamine Copolymers

  , JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, Vol: 131, Pages: 10814-+, ISSN: 0002-7863
  • Author Web Link
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  • Citations: 165
• Journal article
  Koppe M, Brabec CJ, Heiml S, Schausberger A, Duffy W, Heeney M, McCulloch Iet al., 2009,

  Influence of Molecular Weight Distribution on the Gelation of P3HT and Its Impact on the Photovoltaic Performance

  , MACROMOLECULES, Vol: 42, Pages: 4661-4666, ISSN: 0024-9297
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  • Citations: 141
• Journal article
  Kao CY, Lee B, Wielunski LS, Heeney M, McCulloch I, Garfunkel E, Feldman LC, Podzorov Vet al., 2009,

  Doping of Conjugated Polythiophenes with Alkyl Silanes

  , ADV FUNCT MATER, Vol: 19, Pages: 1906-1911, ISSN: 1616-301X

  A strong modification of the electronic properties of solution-processable conjugated polythiophenes by self-assembled silane molecules is reported. Upon bulk doping with hydrolized fluoroalkyl trichlorosilane, the electrical conductivity of ultrathin polythiophene films increases by upon to six orders of cm(-1) for poly(2,5-bis(3-tetradecylthiophen-2-yl)thieno[3,2-b]thiophene) (PBTTT) and 50 +/- 20 S cm(-1) for poly(3-hexyl)thiophene (P3HT). Interband optical absorption of the polymers in the doped state is drastically reduced, making these highly conductive films transparent in the visible range. The dopants within the porous polymer matrix are partially crosslinked via a silane self-polymerization mechanism that makes the samples very stable in vacuum and nonpolar environments. The mechanism of SAM-induced conductivity is believed to be based on protonic doping by the free silanol groups available within the partially crosslinked SAM network incorporated in the polythiophene structure. The SAM-doped polythiophenes exhibit an intrinsic sensing effect: a drastic and reversible change in conductivity in response to ambient polar molecules, which is believed to be due to the interaction of the silanol groups with polar analytes. The reported electronic effects point to a new attractive route for doping conjugated polymers with potential applications in transparent conductors and molecular sensors.

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• Journal article
  Chen H-L, Hou J, McCulloch I, Raupp GB, Subramanian Vet al., 2009,

  SPECIAL ISSUE ON FLEXIBLE ELECTRONICS AND DISPLAYS

  , JOURNAL OF DISPLAY TECHNOLOGY, Vol: 5, Pages: 169-171, ISSN: 1551-319X
  • Author Web Link
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  • Citations: 7
• Journal article
  Jimison LH, Toney MF, McCulloch I, Heeney M, Salleo Aet al., 2009,

  Charge-Transport Anisotropy Due to Grain Boundaries in Directionally Crystallized Thin Films of Regioregular Poly(3-hexylthiophene)

  , ADVANCED MATERIALS, Vol: 21, Pages: 1568-+, ISSN: 0935-9648
  • Author Web Link
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  • Citations: 297
• Journal article
  Mayer AC, Toney MF, Scully SR, Rivnay J, Brabec CJ, Scharber M, Koppe M, Heeney M, McCulloch I, McGehee MDet al., 2009,

  Bimolecular Crystals of Fullerenes in Conjugated Polymers and the Implications of Molecular Mixing for Solar Cells

  , ADVANCED FUNCTIONAL MATERIALS, Vol: 19, Pages: 1173-1179, ISSN: 1616-301X
  • Author Web Link
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  • Citations: 372
• Patent
  James M, McCulloch I, Duffy W, May PE, Walker D, Waller DP, Childers RK, Rodman SEet al., 2009,

  Conducting formulation

  , WO 2009049744

  The invention relates to novel formulations comprising an org. semiconductor (OSC) and a conductive additive, to their use as conducting inks for the prepn. of org. electronic (OE) devices, esp. org. photovoltaic (OPV) cells, to methods for prepg. OE devices using the novel formulations, and to OE devices and OPV cells prepd. from such methods and formulations.

  • Abstract
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• Journal article
  DeLongchamp DM, Kline RJ, Jung Y, Germack DS, Lin EK, Moad AJ, Richter LJ, Toney MF, Heeney M, McCulloch Iet al., 2009,

  Controlling the Orientation of Terraced Nanoscale "Ribbons" of a Poly(thiophene) Semiconductor

  , ACS NANO, Vol: 3, Pages: 780-787, ISSN: 1936-0851
  • Author Web Link
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  • Citations: 157
• Journal article
  Bjorklund N, Lill J-O, Rajander J, Osterbacka R, Tierney S, Heeney M, McCulloch I, Coelle Met al., 2009,

  The effects of metal impurities in poly[(2,5-bis(3-decylthiophen-2-yl)thieno[2,3-b]thiophene] on field-effect transistor properties

  , ORGANIC ELECTRONICS, Vol: 10, Pages: 215-221, ISSN: 1566-1199
  • Author Web Link
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  • Citations: 7
• Journal article
  McGehee MD, Mayer AC, Toney MF, Scully SR, Rivnay J, Cates NC, Gysel R, Heeney M, McCulloch Iet al., 2009,

  PHYS 240-Bimolecular crystals and intercalated molecular structures of polymer/fullerene in bulk heterojunction solar cells

  , ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, Vol: 237, ISSN: 0065-7727
  • Author Web Link
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