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@article{Nako:2015:10.1039/c5dt02144h,
author = {Nako, AE and White, AJ and Crimmin, MR},
doi = {10.1039/c5dt02144h},
journal = {Dalton Transactions},
pages = {12530--12534},
title = {Bis(σ-B-H) complexes of copper(i): precursors to a heterogeneous amine-borane dehydrogenation catalyst},
url = {http://dx.doi.org/10.1039/c5dt02144h},
volume = {44},
year = {2015}
}

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TY  - JOUR
AB  - A series of bis(σ-B-H) complexes of copper(i) have been prepared by displacement of arene solvent from a β-diketiminate copper(i) complex by four-coordinate boranes, H3B-L (L = NMe3, lutidine). In the presence of the same copper arene complex, the secondary amine-borane H3B-NMe2H undergoes dehydrogenation. We provide evidence for formation of a heterogengous catalyst from decomposition of the solution species.
AU  - Nako,AE
AU  - White,AJ
AU  - Crimmin,MR
DO  - 10.1039/c5dt02144h
EP  - 12534
PY  - 2015///
SN  - 1477-9226
SP  - 12530
TI  - Bis(σ-B-H) complexes of copper(i): precursors to a heterogeneous amine-borane dehydrogenation catalyst
T2  - Dalton Transactions
UR  - http://dx.doi.org/10.1039/c5dt02144h
UR  - http://hdl.handle.net/10044/1/24644
VL  - 44
ER  -