Citation

BibTex format

@article{Moruzzi:2023:10.1038/s41467-023-39161-6,
author = {Moruzzi, F and Zhang, W and Purushothaman, B and Gonzalez-Carrero, S and Aitchison, CM and Willner, B and Ceugniet, F and Lin, Y and Kosco, J and Chen, H and Tian, J and Alsufyani, M and Gibson, JS and Rattner, E and Baghdadi, Y and Eslava, S and Neophytou, M and Durrant, JR and Steier, L and McCulloch, I},
doi = {10.1038/s41467-023-39161-6},
journal = {Nature Communications},
title = {Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction},
url = {http://dx.doi.org/10.1038/s41467-023-39161-6},
volume = {14},
year = {2023}
}
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TY  - JOUR
AB  - Four solution-processable, linear conjugated polymers of intrinsic porosity are synthesised and tested for gas phase carbon dioxide photoreduction. The polymers’ photoreduction efficiency is investigated as a function of their porosity, optical properties, energy levels and photoluminescence. All polymers successfully form carbon monoxide as the main product, without the addition of metal co-catalysts. The best performing single component polymer yields a rate of 66 μmol h−1 m−2, which we attribute to the polymer exhibiting macroporosity and the longest exciton lifetimes. The addition of copper iodide, as a source of a copper co-catalyst in the polymers shows an increase in rate, with the best performing polymer achieving a rate of 175 μmol h−1 m−2. The polymers are active for over 100 h under operating conditions. This work shows the potential of processable polymers of intrinsic porosity for use in the gas phase photoreduction of carbon dioxide towards solar fuels.
AU  - Moruzzi,F
AU  - Zhang,W
AU  - Purushothaman,B
AU  - Gonzalez-Carrero,S
AU  - Aitchison,CM
AU  - Willner,B
AU  - Ceugniet,F
AU  - Lin,Y
AU  - Kosco,J
AU  - Chen,H
AU  - Tian,J
AU  - Alsufyani,M
AU  - Gibson,JS
AU  - Rattner,E
AU  - Baghdadi,Y
AU  - Eslava,S
AU  - Neophytou,M
AU  - Durrant,JR
AU  - Steier,L
AU  - McCulloch,I
DO  - 10.1038/s41467-023-39161-6
PY  - 2023///
SN  - 2041-1723
TI  - Solution-processable polymers of intrinsic microporosity for gas-phase carbon dioxide photoreduction
T2  - Nature Communications
UR  - http://dx.doi.org/10.1038/s41467-023-39161-6
UR  - https://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=PARTNER_APP&SrcAuth=LinksAMR&KeyUT=WOS:001003866300008&DestLinkType=FullRecord&DestApp=ALL_WOS&UsrCustomerID=a2bf6146997ec60c407a63945d4e92bb
UR  - https://www.nature.com/articles/s41467-023-39161-6
UR  - http://hdl.handle.net/10044/1/114198
VL  - 14
ER  -
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